General Method for the Asymmetric Synthesis of N–H Sulfoximines via C–S Bond Formation
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چکیده
منابع مشابه
Rhodium-catalyzed direct synthesis of unprotected NH-sulfoximines from sulfoxides.
A novel rhodium-catalyzed imination of sulfoxides using O-(2,4-dinitrophenyl)hydroxylamine is developed under mild conditions with good functional group tolerance. This method provides an efficient access to free NH-sulfoximines, an important structural unit in a variety of biologically active compounds.
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ژورنال
عنوان ژورنال: Organic Letters
سال: 2020
ISSN: 1523-7060,1523-7052
DOI: 10.1021/acs.orglett.0c00761